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Publications

2025

Tolba, A.H.; El-Zohry, A.M.; Khan, J.I.; Svobodová, E.; Chudoba, J.; Klíma, J.; Lušpai, K.; Pižl, M.; Šturala, J.; Cibulka, R., Redox-innocent scandium(III) as the sole catalyst in visible light photooxidations. Nature Communication 2025, 16, 7851. DOI: 10.1038/s41467-025-63233-4
Stitch, M; Pižl, M.; Lehane, N.; Greetham, G.M.; Hartl, F.; Towrie, M.; Quinn, S.J., Eyes on the Prize: Tracking Electron Transfer in G-Rich Duplex and Quadruplex DNA Using Enantiopure Ruthenium Polypyridyl Infrared Redox Probes. Journal of the American Chemical Society 2025 147 (33), 29801-29814. DOI: 10.1021/jacs.5c05736
Kloz, M.; Dostál, J.; Mukherjee, A.; Pižl, M.; Šebesta, F.; Hill, M. G.; Gray, H. B.; Záliš, S.; Vlček, A., Real-Time Tracking of Photoinduced Metal–Metal Bond Formation in a d8d8 Di-Iridium Complex by Vibrational Coherence and Femtosecond Stimulated Raman Spectroscopy. Journal of the American Chemical Society 2025, 147 (11), 9810-9824. DOI: 10.1021/jacs.4c18527

2024

Salati, M.; Dorchies, F.; Wang, J.-W.; Ventosa, M.; González-Carrero, S.; Bozal-Ginesta, C.; Holub, J.; Rüdiger, O.; DeBeer, S.; Gimbert-Suriñach, C.; Durrant, J. R.; Ertem, M. Z.; Gil-Sepulcre, M.; Llobet, A., Covalent Triazine-based Frameworks with Covalently Anchored Ru-tda based Catalyst for Photoinduced Water Oxidation. Small, 2024, 2406375. DOI: 10.1002/smll.202406375
Sumner, E.; Pižl, M.; McQuaid, K. T.; Hartl, F., Nitrile Substituents at the Conjugated Dipyridophenazine Moiety as Infrared Redox Markers in Electrochemically Reduced Heteroleptic Ru(II) Polypyridyl Complexes. Inorganic Chemistry 2024, 63 (5), 2460-2469. DOI: 10.1021/acs.inorgchem.3c03484

2023

Beiler, A.; Denisiuk, A.; Holub, J.; Sanchez-Baygual, F.-J.; Gil-Sepulcre, M.; Ertem, M.; Moonshiram, D.; Piccioni, A.; Llobet, A., Heterogeneous Electrochemical Ammonia Oxidation with a Ru-bda Oligomer Anchored on Graphitic Electrodes via CH-π Interactions. ACS Energy Letters 2023, 8, 172−178. DOI: 10.1021/acsenergylett.2c02483
Bella, G.; Holub, J.; Bruno, G.; Nicolò, F.; Santoro, A., Mononuclear or Coordination Polymer Complexes? Both Are Possible for 3,6,9-Trioxaundecanedioic Acid. Molecules 2023, 28, 7410. DOI: 10.3390/molecules28217410
Štefanková, D.; Skrbek, K.; Pižl, M.; Bartůněk, V., Nano and mesosized selenium and its synthesis using the ascorbic acid route. Journal of Non-Crystalline Solids 2023, 616, 122462. DOI: 10.1016/j.jnoncrysol.2023.122462
Kearney, L.; Brandon, M. P.; Coleman, A.; Chippindale, A. M.; Hartl, F.; Lalrempuia, R.; Pižl, M.; Pryce, M. T., Ligand-Structure Effects on N-Heterocyclic Carbene Rhenium Photo- and Electrocatalysts of CO₂ Reduction. Molecules 2023, 28 (10), 4149. DOI: 10.3390/molecules28104149

2022

Vereshchuk, N.; Gil-Sepulcre, M.; Ghaderian, A.; Holub, J.; Gimbert-Suriñach, C.; Llobet, A., Metamorphic oxygen-evolving molecular Ru and Ir catalysts. Chemical Society Review 2022, 52, 196-211; DOI: 10.1039/D2CS00463A
Pižl, M.; Hunter, B. M.; Sazanovich, I. V.; Towrie, M.; Gray, H. B.; Záliš, S.; Vlček, A., Excitation-Wavelength-Dependent Photophysics of d8d8 Di-isocyanide Complexes. Inorganic Chemistry 2022, 61 (6), 2745-2759. DOI: 10.1021/acs.inorgchem.1c02645
Pavlovska, T.; Lesný, D.K.; Svobodova, E.; Hoskovcova, I.; Archipowa, N.; Kutta, R.J.; Cibulka, R.; Tuning Deazaflavins Towards Highly Potent Reducing Photocatalysts Guided by Mechanistic Understanding – Enhancement of the Key Step by the Internal Heavy Atom Effect. Chemistry – A European Journal 2022, 28, e202200768. DOI: 10.1002/chem.202200768

2021

Taylor, J. O.; Pižl, M.; Kloz, M.; Rebarz, M.; McCusker, C. E.; McCusker, J. K.; Záliš, S.; Hartl, F.; Vlček, A., Optical and Infrared Spectroelectrochemical Studies of CN-Substituted Bipyridyl Complexes of Ruthenium(II).Inorganic Chemistry 2021, 60 (6), 3514-3523. DOI: 10.1021/acs.inorgchem.0c03579

2020

Sondermann, C.; Pižl, M.; Paretzki, A.; Feil, C.; Ringenberg, M. R.; Záliš, S.; Kaim, W., Analysis of a Diimine-Organonickel Redox Series. European Journal of Inorganic Chemistry 2020, 2020 (31), 3010-3015. DOI: 10.1002/ejic.202000455
Pižl, M.; Picchiotti, A.; Rebarz, M.; Lenngren, N.; Yingliang, L.; Záliš, S.; Kloz, M.; Vlček, A., Time-Resolved Femtosecond Stimulated Raman Spectra and DFT Anharmonic Vibrational Analysis of an Electronically Excited Rhenium Photosensitizer. The Journal of Physical Chemistry A 2020, 124 (7), 1253-1265. DOI: 10.1021/acs.jpca.9b10840
Guricová, M.; Tobrman, T.; Pižl, M.; Žižková, S.; Hoskovcová, I.; Dvořák, D., Synthesis, characterisation and electrochemical properties of Cr(0) aminocarbene complexes containing condensed heteroaromatic moiety. J Organomet Chem 2020, 905, 121023. DOI: 10.1016/j.jorganchem.2019.121023

2019

Takematsu, K.; Pospíšil, P.; Pižl, M.; Towrie, M.; Heyda, J.; Záliš, S.; Kaiser, J. T.; Winkler, J. R.; Gray, H. B.; Vlček, A., Hole Hopping Across a Protein–Protein Interface. The Journal of Physical Chemistry B 2019, 123 (7), 1578-1591. DOI: 10.1021/acs.jpcb.8b11982
Hoskovcová, I.; Ludvík, J., Electrochemical approach to Fischer carbene complexes. Current Opinion in Electrochemistry 2019, 15, 165-174. DOI: 10.1016/j.coelec.2019.06.005
Zelenka, J.; Svobodová, E.; Tarábek, J.; Hoskovcová, I.; Boguschová, V.; Bailly, S.; Sikorski, M.; Roithová, J.; Cibulka, R., Combining Flavin Photocatalysis and Organocatalysis: Metal-Free Aerobic Oxidation of Unactivated Benzylic Substrates. Organic Letters 2019, 21 (1), 114-119. DOI: 10.1021/acs.orglett.8b03547

2018

Mojr, V.; Pitrová, G.; Straková, K.; Prukała, D.; Brazevic, S.; Svobodová, E.; Hoskovcová, I.; Burdziński, G.; Slanina, T.; Sikorski, M.; Cibulka, R., Flavin Photocatalysts for Visible-Light [2+2] Cycloadditions: Structure, Reactivity and Reaction Mechanism. ChemCatChem 2018, 10 (4), 849-858. DOI: 10.1002/cctc.201701490
Chen, L.; Lim, K. J. C.; Babra, T. S.; Taylor, J. O.; Pižl, M.; Evans, R.; Chippindale, A. M.; Hartl, F.; Colquhoun, H. M.; Greenland, B. W., A macrocyclic receptor containing two viologen species connected by conjugated terphenyl groups. Organic & Biomolecular Chemistry 2018, 16 (27), 5006-5015. DOI: 10.1039/C8OB00919H
Murašková, V.; Dušek, M.; Buryi, M.; Laguta, V.; Huber, Š.; Sedmidubský, D., Synthesis, characterization and X-ray crystal structure of an iron(III) complex of a tripodal pyridoxal Schiff base ligand: effects of positional disorder on its magnetic properties, Transit. Met. Chem. 2018, 43, 605-619. DOI: 10.1007/s11243-018-0249-x
Pižl, M.; Jankovský, O.; Guricová, M.; Hoskovcová, I.; Sedmidubský, D.; Bartůněk, V., Mixed Yttrium–Ytterbium–Erbium Schiff Base Complex as a Model Precursor for Mixed Nanosized Rare Earths Oxides. Journal of Cluster Science 2018, 29 (4), 549-553. DOI: 10.1007/s10876-018-1393-3
Guricová, M.; Pižl, M.; Smékal, Z.; Nádherný, L.; Čejka, J.; Eigner, V.; Hoskovcová, I., Template synthesis and structure of Co(II), Ni(II), and Cu(II) complexes with pyridoxilydenetaurinate Schiff base ligand. Inorganica Chimica Acta 2018, 477, 248-256. DOI: 10.1016/j.ica.2018.03.031

2017

Pižl, M.; Hunter, B. M.; Greetham, G. M.; Towrie, M.; Záliš, S.; Gray, H. B.; Vlček, A., Ultrafast Wiggling and Jiggling: Ir2(1,8-diisocyanomenthane)42+. The Journal of Physical Chemistry A 2017, 121 (48), 9275-9283. DOI: 10.1021/acs.jpca.7b10215
Murašková, V.; Szabó, N.; Pižl, M.; Hoskovcová, I.; Dušek, M.; Huber, Š.; Sedmidubský, D., Self assembly of dialkoxo bridged dinuclear Fe(III) complex of pyridoxal Schiff base with CC bond formation – Structure, spectral and magnetic properties. Inorganica Chimica Acta 2017, 461, 111-119. DOI: 10.1016/j.ica.2017.02.014
Pižl, M.; Jankovský, O.; Ulbrich, P.; Szabó, N.; Hoskovcová, I.; Sedmidubský, D.; Bartůněk, V., Facile preparation of nanosized yttrium oxide by the thermal decomposition of amorphous Schiff base yttrium complex precursor. Journal of Organometallic Chemistry 2017, 830, 146-149. DOI: 10.1016/j.jorganchem.2016.12.018

2016

Langmaier, J.; Pižl, M.; Samec, Z.; Záliš, S., Extreme Basicity of Biguanide Drugs in Aqueous Solutions: Ion Transfer Voltammetry and DFT Calculations. The Journal of Physical Chemistry A 2016, 120 (37), 7344-7350. DOI: 10.1021/acs.jpca.6b04786
Váňová, H.; Tobrman, T.; Hoskovcová, I.; Dvořák, D., Modular Synthesis of Fischer Biscarbene Complexes of Chromium. Organometallics, 2016, 35(17), 2999-3006. DOI: 10.1021/acs.organomet.6b00527

2015

Metelková, R.; Hoskovcová, I.; Polášek, M.; Urban, J.; David, T.; Ludvík, J., Stereoisomeric products of electrochemical reduction of heterocyclic Fischer aminocarbene Cr(0) complexes. Development of the electrochemistry-mass spectrometry tandem approach using biphasic (acetonitrile-hexane) preparative electrolysis. Electrochimica Acta 2015, 162, 17-23. DOI: 10.1016/j.electacta.2014.10.110

2014

Kvapilová, H.; Hoskovcová, I.; Ludvík, J.; Záliš, S.; Theoretical Predictions of Redox Potentials of Fisher-Type Chromium Aminocarbene Complexes. Organometallics, 2014, 33, 4964-4972. DOI: 10.1021/om500259u
Kvapilová, H.; Eigner, V.; Hoskovcová, I.; Tobrman, T.; Čejka, J.; Záliš, S.; Structural flexibility of 2-hetaryl chromium aminocarbene complexes: Experimental and theoretical evidence. Inorganica Chimica Acta 2014, 421, 439-445. DOI: 10.1016/j.ica.2014.06.028

Kapitola ve sborníku

ELECTROCHEMISTRY OF FISCHER AMINOCARBENE
COMPLEXES: EFFECTS OF STRUCTURE ON REDOX
PROPERTIES, ELECTRON DISTRIBUTION, AND
REACTION MECHANISMS
Jiří Ludvík, Irena Hoskovcová
Chapter 48, p.653-665 in:
Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book,
First Edition. Edited by Armando J. L. Pombeiro.
© 2014 John Wiley & Sons, Inc. Published 2014 by John Wiley & Sons, Inc.
DOI: 10.1002/9781118742952.ch48

Updated: 27.8.2025 20:48, Author: Martin Pižl