Electrochemistry of chromium and iron Carbene complexes (colaboration with Dep. of organic chemistry UCT Prague and J. Heyrovský institute of physical chemistry of CAS)
- relationship between structure and redox properties
- study of mechanism electrochemical reduction and oxidation using spektroelectrochemistry methods (UV-Vis, IR, MS)
- theoretical calculations of distributions and energies of molecular orbitals (HOMO and LUMO)
Synthesis and characterization of complexes containing Schiff base ligand derived from vitamins B
- study of effects for reaction between metal and ligand, synthesis compounds close to the biomolecules
- influence of central atom
- effect of reaction conditions
- determinations the rate stability of complexes using spectroscopic and electrochemical methods